Grignard Reagents

Identity: Industrial chemical speciality

Synonyms: Chloromethylmagnesium

Synonyms: Methyl magnesium Chloride, Chloromethyl magnesium, Chloro (Methyl)Magnesium

CAS No: 676-58-4

Uses:

• Used as alkylating agent in organic synthesis and as a Grignard reagent.
• Also used to make tetramethyl lead, Styr allyl, and pharmaceuticals.

Identity: Industrial chemical speciality

Synonyms: bromomethyl- magnesium

Synonyms: Methyl magnesium Bromide, Methyl Magnesium Bromide, Bromomethyl-Magnesium; Carbanide; Bromide

CAS No: 75-16-1

Uses:

• Used as alkylating agent in organic synthesis and as a Grignard reagent.
• Also used to make tetramethyl lead, Styr allyl, and pharmaceuticals.

Identity: Industrial chemical speciality

Synonyms: Methyl magnesium Bromide, Methyl Magnesium Bromide, Bromomethyl-Magnesium; Carbanide; Bromide

Synonyms:

CAS No: 1826-67-1

Uses:

• Vinyl magnesium bromide solution (1 M in THF) may be used in the synthesis of 2-vinylchroman-4-ones by the conjugate addition with chromones in the presence of a Lewis acid.
• It may also be used in the following transformations: 1. (S)-3-(benzyloxy)-4-oxo-butanoic acid methyl ester to methyl (3S,4S)-4-hydroxy-3-(phenyl methoxy) hex-5-enoate. 2. (R)-1-Azido-5,6-epoxyhexane to (S)-1-(4-azidobutyl)-2-propen-1-ol. 3. 2,3-O-Isopropylidene-D-ribose to 1-[(4R,5S)-5-((1S)-1-hydroxyallyl)-2,2-dimethyl[1,3] dioxolan-4-yl]ethane-1,2-diol. 4. (4S,5S)-2,2-Dimethyl-5-vinyl [1,3]dioxolane-4-carbaldehyde to (1R,4R,5S)- and (1S,4R,5S)-1-(2,2-dimethyl-5-vinyl[1,3]dioxolan-4-yl)prop-2-en-1-ol. 5. Ethyl levulinate to ?-methyl-?-vinyl butyrolactone.

Identity: Industrial chemical speciality

Synonyms: Chlorophenylmagnesium

Synonyms: Phenyl magnesium Chloride , Chlorophenyl-Chlorophenyl magnesium

CAS No: 100-59-4

Uses:

• Used as a Grignard reagent and in organic synthesis (hydrocarbons, alcohols, ketones, organic acids, amines, silicones, boranes, pesticides, and organotin compounds).

Identity: Industrial chemical speciality

Synonyms: Bromophenylmagnesium

Synonyms: Phenyl magnesium Chloride , Chlorophenyl-Chlorophenyl magnesium

CAS No: 100-59-4

Uses:

• Used as a Grignard reagent and in organic synthesis.

Identity: Industrial chemical speciality

Synonyms: chloro(phenylmethyl)-magnesium

Synonyms: (Phenylmethyl)magnesium chloride, Benzyl chloro magnesium, Chloro(phenylmethyl)magnesium

CAS No: 6921-34-2

Uses:

• Benzylmagnesium chloride (Grignard reagent) can be used as an alkylating reagent:
• For alkylating quinolyl-functionalized Cp−chromium (III) complexes which are used as precursors for the preparation of active olefin polymerization catalysts.
• In the synthesis of 2,3-disubstituted benzopyran-4-ones, 6-chloro-8-methylpurine derivative, and phenylalanine derivatives.